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(14 People Likes) Why is the 5th ionization energy of phosphorus significantly lower than that of silicon?
,[math]Z_{\text{the atomic number}}=14[/math],and ATOMIC phosphorus,[math]Z_{\text{the atomic num full silicone sex doll er}}=15[/math]. [math]\underbrace{1s^{2}2s^{2}2p^{6}3s^{2}3p^{2}}_{\text{electronic configuration of Si atom,Z=14}}[/math] [math]\underbrace{1s^{2}2s^{2}2p^{6}3s^{2}3p^{3}}_{\text{electronic configuration of P atom,Z=15}}[/math] Now to get to [math]Si^{4+}(g)[/math] we REMOVE ALL the [math]3s[/math],and [math]3p[/math],valence electrons..an energetic process… On the other hand,its FIFTH ionization event,requires removal of an inner core [math]2p[/math] electron … and this should have a greater energy cost than the fifth ionization of phosphorus,for which a [math]3s[/math]
(88 People Likes) I started birth control when I was 13 for my period symptoms. My breasts were still developing,and one was bigger than the other. My left breast never caught up with the right. Could the birth control have affected the growth?
n’s breasts are radically diffe Love Doll ent sizes. For now,you can buy a bra to fit the larger breast,then put a silicone prosthesis in the cup full silicone sex doll so the smaller breasts look the same. If you go to a specialty brassiere shop,they can fit you properly and show you how to fix it
(85 People Likes) Zack Snyder just announced the Snyder Cut of Justice League. What's your reaction to it?
o do well. Does the Snyder cut fall firmly in that territory? Well,let's find out. Firstly,we need to remember that the DCEU never got off to a very satisfying start. It was shaky foundations. Man of Steel has a lot ot haters. BvS has a lot of haters. Justice League 2017 has a lot of haters. And all this primarily because Warner Bros were rushing things,desperately trying to catch up with Marvel's success. We have all heard reports of studio's interference with the directors' original vision and how that resulted in an overall inferior theatrical product on multiple occasions— the biggest examples being Suicide Squad and Justice League 2017. Fans were angry,and rightfully so. They didn't think they were getting the cinematic versions of their favourite characters which they deserved. The Snyder cut is still a product of its time. It has the daunting task of carrying on the legacy of something which started off on questionable foundations. To have a fair evaluation of this movie,it is very important to keep in mind this fact. Plus,there are not a lot of surprises this movie can pull off in the plot department,because overall the plots of the Snyder cut and the 2017 theatrical version are the same. And considering these handicaps,I think the movie did quite well actually. There is more runtime- every character gets its time in the sun thanks to a nearly 4 hours screentime real estate. There is a very good Cyborg arc. He is the heart,the emotional core of the movie. Joss Whedon really did a vast disservice to this character in the 2017 theatrical version. The Realistic Sex Doll nyder cut handles this character,portrayed earnestly by Ray Fisher,very very well. Wonder Woman is badass. Snyder really nails the badassery of this worldwide icon of female strength and glory in his movies. WW was badass in BvS. She is badass here. And Gal Gadot is phenomenal in her portrayal of this iconic character. Her body language,her demeanor,the fleeting microexpressions on her face — all make for a very likeable and credible Wonder Woman. Batman gets a redemption arc. This is not really much different than 2017 cut. It was handled in a serviceable fashion there. That gets carried over to the Snyder cut. What constitutes an improvement is the character of Alfred and the banter which Bruce and Alfred exchange. There is humour and sarcasm. At one point,Batman even introduces Alfred to the rest of the league saying,“This is Alfred. I work for him.” 😉 Aquaman is handled slightly better here compared to the 2017 version. Due to the increased runtime,we get to see more of the heroic qualities of compassion and empathy within him. Joss Whedon had reduced him to a fairly unidimensional ‘bad boy’ superhero character. It was okay,but felt shallow. It's refreshing to see the original vision Snyder had for him. And this is a recurrent theme in the Snyder cut. The characters get justice. They are handled with love and care and thoughtfulness. For a fan of the Justice League animated series,which used to air in Cartoon Network,this is more of what we want to see in a live action version of these characters. Superman is handled well. The movie starts with him and the opening montage is beautiful. Zac Snyder shines in his unique way of visual storytelling. The movie gets to a very interesting start. Superman doesn't have a lot of screen time. But his involvement is very crucial to the plot of the movie. The director plays that card effectively. Superman isn't allowed to overshadow anyone else. Neither does he feel redundant in the movie. I also really liked how Superman's arc in the Snyder cut really tied into very neatly with Man of Steel and BvS. It felt like a culmination of the story elements which were set into motion in the previous two movies. And this very fact elevates the Snyder cut in my eyes. The director's original vision was to make Justice League complete the character arc of Kal-El which started in Man of Steel. And in this regard,it feels really satisfying. Superman grows more into the Superman fans love and respect by the end of this movie — cheery,hopeful,decisive and all-round positive attitude. If we pause to consider that Justice League was what Snyder originally envisioned as a conclusion of a three-part arc for Superman,which began with MoS,transitioned through BvS and got fully realized in JL,then perhaps a lot of choices which the creative team made in the earlier two movies kind of start making more sense. His brooding nature in MoS,his self-doubts and the general anxiety he caused in the world with his god-like powers and elevating into selfless martyrdom in BvS,and finally coming back in JL as a much better version of himself- all start making more sense. Superman cheerily says to Lois in the movie that he has now a second chance and he isn't going to waste it. I am with him on this one. Flash probably didn't get handled so well. He was presented as wimpy and ineffectual. He was tried as comic relief but even that didn't work for me that well. He does get partially redeemed in my eyes though in the final act. He does something which was visually awesome to behold and changed the tide of the movie. His moments with his father were handled well. His rescuing Iris was done well. But overall this movie didn't do him justice. He didn't feel like a fleshed out superhero. However,we need to keep in mind that when Snyder was making this movie,a solo Flash movie was in the works. Maybe the solo Flash movie would have served to complete his arc from a wimpy man-child to a full-blown superhero. But I guess now we shall never know for sure because DCEU has taken a new path post release of 2017 Justice League and its disappointing BO performance. The villain was more badass! Steppenwolf got an upgrade. He even got a little backstory which fleshed him out more. Darkseid made an appearance. The concept of using Steppenwolf as kind of a herald for a far darker and menacing villain Darkseid was handled really effectively. Steppenwolf mostly gets the generic villain treatment but we need to understand that unlike Infinity War,where all the superheroes had already been introduced earlier,Justice League was meant to introduce us to many new characters,who'd be getting their own movies down the road. A questionable strategy,all borne out of DC's desperation to match and catch up to Marvel's success. But within the framework of this strategy,Snyder had to operate and so he couldn't afford to have a villain like Thanos overshadow the heroes in terms of being more interesting. So keeping a generic villain profile for Steppenwolf works in this movie considering the context of the overall studio strategy it works in. There are pacing issues in the movie though. Sometimes the movie feels slow. I don't fault it for this,because originally it was meant to be streamed in 6 chapters. But then it was decided to release everything at one go. This movie is visual eye-candy! Snyder has a penchant for creating compelling visuals and this movie packs a whallop on that front. Action scenes are breathtaking and create a super-immersive experience. The Flash's powers are depicted in a very cool way. Cyborg's discovery of his abilities was handled very imaginatively. The exposition scenes got a real facelift because of the director's unique way of visual storytelling. And Snyder uses music and songs to uplift the visual imagery. The combination of audio and visuals worked well for me for the most part. This movie has cliffhangers and hooks for the future. A future which might never get realised now. And that makes me sad. And this is where I am deciding whether the movie had more strengths than weaknesses. If a movie makes me excited for more,then it has done more right than wrong. And right now I really wish I could see more of how Snyder decided to use Darkseid as a future Justice League villain. There is also the hook of a dystopian timeline where Superman becomes the antagonist and Batman has to band together with villains and heroes alike to face him. It piqued my interest as well. So,all in all,despite the runtime and certain questionable choices which the creative team made,I still like this movie. The Snyder's Cut definitely doesn't feel redundant. Fans deserved this rendition. And whether or not WB gives Snyder a chance or not
(11 People Likes) What can you bring to Harvard?
are provided. Some people bring furniture like couches,TVs,video game consoles,etc. The main restrictions are that you cannot bring microwaves,hotplates,or any other cooking appliances: only the Harvard-approved micro-fridge combo is allowed,which you can rent from the University. This is for fire-safety reasons. Then there are the usual restrictions on weapons and explosives,illegal drugs,and pets (sorry,the dog stays at home!),though I'm sure some smaller,non
(41 People Likes) If annabelle doll is real,then are ghosts and spirits real?
oll is just a creation of a script writer of a horror film and nothing else. It has nothing to do with ghosts or spirits. How can a annabelle doll define that is it is real then ghost are real? Ghost are not real and neither is annabelle but spirits are real. They exist and no science has the power to deny it vehemently. They deny it but are totally silent on hearing about some unexplained phenomenon concerning spir
